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标题:Synergistic and Selective Copper/ppm Pd-Catalyzed Suzuki-Miyaura Couplings: In Water, Mild Conditions, with Recycling
时间:2020-03-26 13:27:53
DOI:10.1021/acscatal.6b02809
作者:Handa, Sachin; Smith, Justin D.; Hageman, Matthew S
关键词:Suzuki−Miyaura couplings;E Factors;green chemistry;micellar catalysis;copper catalysis
出版源: 《Acs Catalysis》 :acscatal.6b02809
摘要:Copper-catalyzed Suzuki-Miyaura couplings can be carried out exclusively on aryl iodides under very mild conditions made possible by synergistic effects due to the presence of ppm levels of palladium as co-catalyst. The coupling requires a hemi-labile P(O)-N ligand, together with the benefits of micellar catalysis using water as the recyclable reaction medium.
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