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标题:ChemInform Abstract: PHEROMONES. PART 4. KOLBE SYNTHESIS OF 3,11-DIMETHYL-2-NONACOSANONE, A PHEROMONE OF THE GERMAN COCKROACH BLATTELLA GERMANICA
时间:2020-03-26 13:11:10
DOI:10.1002/chin.198018330
作者:SEIDEL, W;SCHAEFER, H. J
关键词:other bioactive products
出版源: 《Chemischer Informationsdienst》 ,1980
摘要:react-text: 152 The pure four stereoisomers of 3,ll-dimethyl-2-nonacosanone (1), the female-produced sex pheromone of the German cockroach, were synthesized starting from (R)-citronellol (2a) and ethyl (R)-3-hydroxybutanoate (3). The key step was the chromatographic separation of (5RS,6R)-6-hydroxy-5-methyl-2-heptanone (16a) to give pure (5R,6R- and) 5S,6R-isomers. All of the four stereoisomers of 1 were... /react-text react-text: 153 /react-text [Show full ]
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