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标题:Asymmetric Synthesis of Triarylmethanes by Rhodium-Catalyzed Enantioselective Arylation of Diarylmethylamines with Arylboroxines
时间:2019-12-03 08:17:32
DOI:10.1021/jacs.5b03277
作者:Yinhua Huang;Tamio Hayashi
关键词:polyphenylalkane derivatives;C〤 bond formation;catalysis, phase‐transfer catalysis;diastereoselective syntheses, enantioselective syntheses (incl. cis/trans﹊somerism;intermediates (and their reactions
出版源: 《Journal of the American Chemical Society》 ,2015 ,137 (24) :7556-9
摘要:Abstract This novel reaction is assumed to proceed through o-quinone methide intermediates, which undergo Rh-catalyzed asymmetric 1,4-addition of the arylboron reagents.
大小:536 kb
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