标题: | Asymmetric Synthesis of Triarylmethanes by Rhodium-Catalyzed Enantioselective Arylation of Diarylmethylamines with Arylboroxines |
时间: | 2019-12-03 08:17:32 |
DOI: | 10.1021/jacs.5b03277 |
作者: | Yinhua Huang;Tamio Hayashi |
关键词: | polyphenylalkane derivatives;C〤 bond formation;catalysis, phase‐transfer catalysis;diastereoselective syntheses, enantioselective syntheses (incl. cis/trans﹊somerism;intermediates (and their reactions |
出版源: | 《Journal of the American Chemical Society》 ,2015 ,137 (24) :7556-9 |
摘要: | Abstract This novel reaction is assumed to proceed through o-quinone methide intermediates, which undergo Rh-catalyzed asymmetric 1,4-addition of the arylboron reagents. |
大小: | 536 kb |
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