| 标题： | Asymmetric Synthesis of Triarylmethanes by Rhodium-Catalyzed Enantioselective Arylation of Diarylmethylamines with Arylboroxines |
| 时间： | 2019-12-03 08:17:32 |
| DOI： | 10.1021/jacs.5b03277 |
| 作者： | Yinhua Huang;Tamio Hayashi |
| 关键词： | polyphenylalkane derivatives;C〤 bond formation;catalysis, phase‐transfer catalysis;diastereoselective syntheses, enantioselective syntheses (incl. cis/trans﹊somerism;intermediates (and their reactions |
| 出版源： | 《Journal of the American Chemical Society》 ,2015 ,137 (24) :7556-9 |
| 摘要： | Abstract This novel reaction is assumed to proceed through o-quinone methide intermediates, which undergo Rh-catalyzed asymmetric 1,4-addition of the arylboron reagents. |
| 大小： | 536 kb |
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